709-27 heavy duty – clear cement Tube 60ml
PVC HEAVY DUTY CLEAR
1. Identification
Product identifier PVC Heavy Duty Clear or Gray Cement Other means of identification
SDSnumber 1102E
Synonyms Part Numbers: Clear 30850, 30863, 30876(TV), 30882, 31008(TV), 31011, 31950, 31951,31952,
31953 Gray 30349, 31093, 31094, 31095, 31105, 31118, 31978, 31979, 31980, 31981, 32050,
32051, 32052, 32210, 32211
Recommendeduse Joining PVC Pipes
Recommendedrestrictions None known.
2. Hazard(s) identification
Physical hazards Healthhazards
OSHA defined hazards Labelelements
Flammable liquids
Acute toxicity, oral Skincorrosion/irritation
Serious eye damage/eye irritation
Specific target organ toxicity, single exposureSpecific target organ toxicity, single exposureAspiration hazard
Not classified.
Category2
Category4
Category 2 Category 2A
Category 3 respiratory tract irritation Category 3 narcotic effects Category 1
Signalword Danger
Hazardstatement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness ordizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Use only outdoors or in a well-ventilated area. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/faceprotection.
Response Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media toextinguish.
Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store lockedup.
Disposal Dispose of contents/container in accordance with local/regional/national/internationalregulations.
Hazard(s) not otherwise classified (HNOC)
Supplemental information
Not applicable.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen.
3. Composition/information on ingredients
Mixtures
Chemical name | CAS number | % |
Furan, Tetrahydro- | 109-99-9 | 30-60 |
2-Propanone | 67-64-1 | 10-30 |
Cyclohexanone | 108-94-1 | 10-30 |
Polyvinyl chloride | 9002-86-2 | 10-30 |
Methyl ethyl ketone | 78-93-3 | 5-10 |
Colloidal silicon dioxide | 112945-52-5 | 1-5 |
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feelunwell.
Skincontact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Eyecontact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medicaladvice/attention.
Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn’t get into the lungs. Aspiration may cause pulmonary edema andpneumonitis.
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Generalinformation Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing beforereuse.
5. Fire-fighting measures
Suitableextinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire fighting equipment/instructions
Do not use water jet as an extinguisher, as this will spread the fire.
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk.
Specificmethods Use standard firefighting procedures and consider the hazards of other involved materials.
Generalfire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or withage.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmentalprecautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions forsafe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly afterhandling.
Conditions for safe storage, including any incompatibilities
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with sprinklers.
8. Exposure controls/personal protection
Occupational exposure limits
U.S. – OSHA
Components
Type
Value
Form
Colloidal silicon dioxide (CAS 112945-52-5)
TWA 0.8 mg/m3 Unspecified.
20mppcf Unspecified.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Components | Type | Value |
Polyvinyl chloride (CAS 9002-86-2) | STEL | 5 ppm |
TWA | 1 ppm |
- OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Form
2-Propanone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
PEL 2400 mg/m3
1000 ppm
PEL 200 mg/m3
50 ppm
PEL 590 mg/m3
200 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components | Type | Value | Form |
Methyl ethyl ketone (CAS 78-93-3) | PEL | 590 mg/m3 | |
200 ppm | |||
Polyvinyl chloride (CAS 9002-86-2) | PEL | 5 mg/m3 | Respirable fraction. |
15 mg/m3 | Total dust. | ||
US. OSHA Table Z-3 (29 CFR 1910.1000) | |||
Components | Type | Value | |
Colloidal silicon dioxide (CAS 112945-52-5) | TWA | 0.8 mg/m3 | |
20 mppcf | |||
US. ACGIH Threshold Limit Values | |||
Components | Type | Value | Form |
2-Propanone (CAS 67-64-1) | STEL | 750 ppm | |
TWA | 500 ppm | ||
Cyclohexanone (CAS 108-94-1) | STEL | 50 ppm | |
TWA | 20 ppm | ||
Furan, Tetrahydro- (CAS 109-99-9) | STEL | 100 ppm | |
TWA | 50 ppm | ||
Methyl ethyl ketone (CAS 78-93-3) | STEL | 300 ppm | |
TWA | 200 ppm | ||
Polyvinyl chloride (CAS 9002-86-2) | TWA | 1 mg/m3 | Respirable fraction. |
U.S. – NIOSH | |||
Components | Type | Value | Form |
Colloidal silicon dioxide (CAS 112945-52-5) | REL | 6 mg/m3 | Unspecified. |
US. NIOSH: Pocket Guide to Chemical Hazards | |||
Components | Type | Value | |
2-Propanone (CAS 67-64-1) | TWA | 590 mg/m3 | |
250 ppm | |||
Colloidal silicon dioxide (CAS 112945-52-5) | TWA | 6 mg/m3 | |
Cyclohexanone (CAS 108-94-1) | TWA | 100 mg/m3 | |
25 ppm | |||
Furan, Tetrahydro- (CAS 109-99-9) | STEL | 735 mg/m3 | |
250 ppm | |||
TWA | 590 mg/m3 | ||
200 ppm | |||
Methyl ethyl ketone (CAS 78-93-3) | STEL | 885 mg/m3 | |
300 ppm | |||
TWA | 590 mg/m3 | ||
200 ppm |
Biological limit values
ACGIH Biological Exposure Indices
Components | Value | Determinant | Specimen | Sampling Time |
2-Propanone (CAS 67-64-1) | 50 mg/l | Acetone | Urine | * |
Cyclohexanone (CAS 108-94-1) | 80 mg/l | 1,2-Cyclohexan ediol, with hydrolysis | Urine | * |
8 mg/l | Cyclohexanol, with hydrolysis | Urine | * | |
Furan, Tetrahydro- (CAS 109-99-9) | 2 mg/l | Tetrahydrofura n | Urine | * |
Methyl ethyl ketone (CAS 78-93-3) | 2 mg/l | MEK | Urine | * |
* – For sampling details, please see the source document.
Exposure guidelines
US – California OELs: Skin designation
Cyclohexanone(CAS 108-94-1) Can be absorbed through the skin.
US – Minnesota Haz Subs: Skin designation applies
Cyclohexanone(CAS 108-94-1) Skin designation applies.
US – Tennessee OELs: Skin designation
Cyclohexanone(CAS 108-94-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone(CAS 108-94-1) Can be absorbed through the skin.
Furan, Tetrahydro-(CAS 109-99-9) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone(CAS 108-94-1) Can be absorbed through the skin.
Appropriate engineering controls
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/faceprotection Wear safety glasses with side shields (or goggles).
Skin protection
Handprotection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistantclothing.
Respiratoryprotection If engineering controls do not maintain airborne concentrations below recommendedexposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must beworn.
Thermalhazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations
When using, do not eat, drink or smoke. Wash hands after handling and before eating.
9. Physical and chemical properties
Appearance Opaque.or Translucent.
Physicalstate Liquid.
Form Liquid.
Color Gray or Clear.
Odor Solvent.
Odorthreshold Not available.
pH Notavailable.
Meltingpoint/freezing point Not available.
Initial boiling point and boiling range
151 °F (66.11 °C)
Flashpoint 14.0 – 23.0 °F (-10.0 – -5.0 °C)
Evaporation rate 5.5 – 8
Flammability(solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit – lower (%)
Flammability limit- upper(%)
Not available. Not available.
Explosive limit -lower (%) Not available.
Explosive limit -upper (%) Not available.
Vaporpressure 145 mm Hg @ 20 C
Vapordensity 2.5
Relativedensity 0.88 – 0.92
Solubility(ies)
Solubility(water) Negligible
Partition coefficient (n-octanol/water)
Auto-ignition temperature Decomposition temperature Viscosity
Other information Bulk density VOC (Weight %)
- Stability andreactivity
Reactivity Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
Notavailable.
Notavailable.
Notavailable.
1200 – 2500 cP
7.5 lb/gal
<510 g/l SQACMD 1168/M316A
The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation May be fatal if swallowed and enters airways. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May cause irritation to the respiratory system.
Skincontact Causes skin irritation.
Eyecontact Causes serious eye irritation.
Ingestion May be fatal if swallowed and enters airways. Harmful ifswallowed.
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Information on toxicological effects
Acutetoxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Components Species
Cyclohexanone (CAS 108-94-1)
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Test Results
948 mg/kg
8000 ppm, 4 hours
Components Species
Oral
LD50 Rat
Test Results
1540 mg/kg
* Estimates for product may be based on additional component data not shown.
Skincorrosion/irritation Causes skin irritation.
Serious eye damage/eye irritation
Respiratory or skin sensitization
Causes serious eye irritation.
Respiratorysensitization Not available.
Skinsensitization This product is not expected to cause skin sensitization.
Germcell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Carcinogenicity Suspected of causing cancer. In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential inhumans.
Therefore, the IRIS review concludes that these data in aggregate indicate that there is “suggestive evidence of carcinogenic potential” following exposure to THF by all routes of exposure. This product contains polyvinyl chloride (PVC) that is not a fabricated product, and is therefore, defined and regulated as a toxic and hazardous substance under 29 C.F.R. § 1910.1017 due to the presumed presence of residual vinyl chloride monomer. The concentrations of residual vinyl chloride calculated to be contained in this product are well below the threshold for classification in accordance with 29 C.F.R. § 1910.1200.
IARC Monographs. Overall Evaluation of Carcinogenicity
Colloidal silicon dioxide(CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans. Cyclohexanone(CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.
Polyvinyl chloride(CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Polyvinyl chloride(CAS 9002-86-2) Cancer
Reproductivetoxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity – single exposure
Specific target organ toxicity – repeated exposure
Respiratory tract irritation. Narcotic effects. Not classified.
Aspirationhazard May be fatal if swallowed and enters airways.
Chroniceffects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.
Components
Cyclohexanone (CAS 108-94-1)
Aquatic
Species
Test Results
Fish
LC50
Fathead minnow (Pimephales promelas)
481 – 578 mg/l, 96 hours
* Estimates for product may be based on additional component data not shown.
Persistenceand degradability No data is available on the degradability of this product.
Bioaccumulativepotential No data available.
Partition coefficient n-octanol / water (log Kow)
2-Propanone(CAS 67-64-1) -0.24
Cyclohexanone (CAS108-94-1) 0.81
Furan, Tetrahydro-(CAS 109-99-9) 0.46
Methyl ethyl ketone(CAS 78-93-3) 0.29
Mobilityin soil No data available.
Otheradverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from thiscomponent.
13. Disposal considerations
Disposalinstructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Localdisposal regulations Dispose in accordance with all applicable regulations.
Hazardouswaste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Waste from residues / unused products
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Contaminatedpackaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Other information, including date of preparation or lastrevision
HMIS®ratings Health: 2 Flammability:3
Physical hazard: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currently available.
Categories HEAVY DUTY CLEAR, PVC & CPVC CEMENT